How to tell them apart (per Section 4.2 of the v1.0 whitepaper): direct interactions are mechanisms that result from the fluid itself — occurring within the fluid (aging, moisture uptake) or where the fluid affects a wetted material — and can lead to failure of a part or the whole system. Indirect interactions do not result from the fluid itself, but from the chemicals released or produced by direct interactions: by-products circulating with the coolant cause failures remote from their source. Two mechanisms — Dissolution and Aging — appear in both OCP tables, because each degrades its immediate target directly and releases by-products that act elsewhere.
Direct Interactions — caused by the fluid itself
Definition: The interaction results from the fluid: it degrades either the wetted component in contact with the fluid, or the fluid's own dielectric performance. The damage appears where the interaction happens.
Mechanisms:
- Dissolution: The fluid leaches soluble constituents — plasticizers from cable jacketing, additives from adhesives and potting compounds — out of the material. The part loses mass, hardens, embrittles, shrinks, and cracks. The dissolved matter also contaminates the shared fluid bath, which is where the indirect risks below begin.
- Absorption / Swelling: Elastomer seals, O-rings, and gaskets absorb the surrounding fluid and expand — softening, losing compression force, and ultimately losing the seal.
- Chemical Interaction: The fluid or its impurities chemically react with the material: corrosion of metals, attack of resins, coatings, and inks.
- Environmental Stress Cracking: Polymers held under mechanical stress (clips, standoffs, tensioned housings) crack in the presence of the fluid at loads far below their normal yield point.
- Aging: The fluid's dielectric properties deteriorate in service — oxidation, accelerated by moisture and elevated temperature, forms free acids and sludge.
- Moisture Intake: The fluid absorbs atmospheric moisture, directly raising its dissipation factor and lowering breakdown voltage — no material interaction required.
Indirect Interactions — caused by released or produced chemicals
Definition: The interaction does not result from the fluid itself, but from chemicals released or produced by direct interactions — oxidation by-products, dissolved additives, extracted residues — circulating in the shared bath and causing failure remote from their source.
Mechanisms:
- Dissolution (by-products): Dissolved materials, additives, or plasticizers carried in the fluid interact with other components — e.g., sulfur leached from rubbers corroding IT equipment.
- Aging (by-products): Oxidation raises the fluid's acid value, and those acids — along with other aging by-products — can attack materials that were compatible with fresh fluid.
System-level risks of a degraded bath:
- Dielectric breakdown: Ionic contaminants (e.g., solder-flux activators dissolved off boards) accumulate in the bath, raising fluid conductivity and eroding the insulation margin around energized components.
- Electrochemical migration: Transported metallic residues deposit on active PCB copper traces, growing conductive dendrites that end in short-circuits.
- Heat-transfer fouling: Extracted plasticizers and oils redeposit on hot component surfaces — particularly two-phase boiling surfaces — forming films that impede heat transfer.
Two-Phase Systems — primary & secondary compatibility
For two-phase fluorochemical fluids, the whitepaper frames the same distinction as primary compatibility (the direct effect of the fluid on a material — fluid–material) and secondary compatibility (one material affecting another using the fluid as a vector — material–material). Boiling amplifies the secondary pathway: non-volatile contaminants concentrate on boiling surfaces by distillation, reducing heat transfer, while freshly distilled condensate aggressively re-extracts contaminants from elastomers. This transport loop is exactly what the Soxhlet extraction screen reproduces in the lab.